Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Electro Chemistry

Question:

If the equivalent conductance of 1 M benzoic acid is 12.8 ohm-1 cm² eq-1 and if the conductance of benzoate ion and H+ ion are 42 and 288.42 ohm-1 cm² eq-1 respectively, what is its degree of dissociation?

Options:

39%

3.9%

0.35%

0.039%

Correct Answer:

3.9%

Explanation:

\(\Lambda _{C_6H_5COOH} = \Lambda _{C_6H_5COO^-} + \Lambda _{H^+}\)

\(\Lambda _{C_6H_5COOH}\)= 42 + 288.42 = 330.42 ohm-1 cm² eq-1 

α = \(\frac{12.8}{330.42}\) x 100 = 3.87 ≈ 3.9%