Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Electro Chemistry

Question:

The electrical resistance is represented by the symbol ‘R’ and it is measured in ohm (Ω) which is in terms of SI. The electrical resistance of any object is directly proportional to its length, l, and inversely proportional to its area of cross section, A.

That is, R ∝ \(\frac{l}{A}\) or R = ρ\(\frac{l}{A}\) 

The constant of proportionality, ρ (Greek, rho), is called resistivity (specific resistance). Its SI units are ohm metre (Ω m) and quite often its submultiple, ohm centimetre (Ω cm) is also used. IUPAC recommends the use of the term resistivity over specific resistance. Physically, the resistivity for a substance is its resistance when it is one metre long and its area of cross section is one m2 .

It can be seen that: 1 Ω m = 100 Ω cm or 1 Ω cm = 0.01 Ω m The inverse of resistance, R, is called conductance, G, and we have the relation:

G = \(\frac{1}{R}\) = \(\frac{A}{ρl}\) = κ\(\frac{A}{l}\). The SI unit of conductance is siemens, represented by the symbol ‘S’ and is equal to ohm–1 (also known as mho) or Ω –1. The inverse of resistivity, called conductivity (specific conductance) is represented by the symbol, κ (Greek, kappa). IUPAC has recommended the use of term conductivity over specific conductance and hence we use the term conductivity. The SI units of conductivity are S m–1 but quite often, κ is expressed in S cm–1. Conductivity of a material in S m–1 is its conductance when it is 1 m long and its area of cross section is 1 m2 . It may be noted that 1 S cm–1 = 100 S m–1 .

What is the SI unit of cell constant (σ)?

Options:

m-1 or cm-1

m-2 or cm-2

m or cm

m2 or cm2

Correct Answer:

m-1 or cm-1

Explanation:

Cell constant, σ = \(\frac{l}{A}\) = m-1 or cm-1