Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: Coordination Compounds

Question:

Assertion: [Ni(CN)4]2- is diamagnetic complex.
Reason: [Ni(CN)4]2- involves dsp2 hybridisation and there is no unpaired electron.

Options:

Assertion and reason both are correct statements and reason is correct explanation for assertion.

Assertion and reason both are correct statements but reason is not correct explanation for assertion.

Assertion is correct statement but reason is wrong statement.

Assertion is wrong statement but reason is correct statement.

Correct Answer:

Assertion and reason both are correct statements and reason is correct explanation for assertion.

Explanation:

In [Ni(CN)4]2- 

x + 4(-1) = -2

x - 4 = -2

x = -2 + 4 = 2

28Ni : [Ar]4s23d8

Ni2+ : [Ar]3d

[Ni(CN)4]2- is diamagnetic complex. It involves dsp2 hybridisation and there is no unpaired electron.