Which of the following statements, with reference to a solution are correct? (A) The osmotic pressure of the solution is proportional to the molarity of the solute. Choose the correct answer from the options given below: |
(A), (B) and (D) only (A) and (B) only (C) and (D) only (B), (C) and (D) only |
(A) and (B) only |
The correct answer is Option (2) → (A) and (B) only Option 1: (A), (B) and (D) only Statement (A) follows van’t Hoff’s equation $\pi = iMRT$, so osmotic pressure is proportional to molarity. (B) is also correct since $\Delta T_b = K_b m$, directly proportional to molality. However (D) is wrong because boiling point elevation is $T_b(\text{solution}) - T_b^\circ(\text{solvent})$, not the reverse. Option 2: (A) and (B) only Both (A) and (B) correctly state colligative property relations: osmotic pressure depends on molarity and boiling point elevation depends on molality. (C) has incorrect units and (D) has the wrong expression sign. So this set fits. Option 3: (C) and (D) only (C) is wrong because the correct unit of $K_b$ is $\text{K kg mol}^{-1}$, not $\text{K kg}^{-1} \text{mol}^{-1}$. (D) also reverses the definition of boiling point elevation. So both are incorrect. Option 4: (B), (C) and (D) only Although (B) is correct, (C) has incorrect units and (D) has the wrong formula sign. Hence the group is incorrect. |