Read the following passage given below and answer the question. Andehydes and ketones undergo nucleophilic addition reactions. A nucleophile attacks the electrophilic carbon atom of polar carbonyl group from perpendicular to plane of \(sp^2\) hybridized orbitals of carbonyl carbon. The hybridization of carbon changes from \(sp^2\) \(sp^3\) and a tetrahedral alkoxide intermediate is formed. This captures \(H^+\) to give neutral product. In carboxylic acids, carbonyl carbon is less electrophilic than carbonyl carbon carbon of aldehydes and ketones. |
How will you convert acetaldehyde to lactic acid? |
treating with \(HCN\) followed by hydrolysis treating with \(CH_3OH\)molecules twice treating with sodium bisulphite and then hydrolyzing treating with \(CH_3MgBr\) followed by hydrolysis |
treating with \(HCN\) followed by hydrolysis |
The correct answer is option 1. treating with \(HCN\) followed by hydrolysis. When acetaldehyde) reacts with hydrocyanic acid (\( \text{HCN} \)), it forms 2-hydroxypropanenitrile (also known as a cyanohydrin) where the hydroxyl group (\( \text{OH} \)) is added to the carbonyl carbon, and the cyanide group (\( \text{CN} \)) is added to the same carbon. The cyanohydrin is then hydrolyzed, typically with acidic conditions. This hydrolysis converts the cyanide group into a carboxyl group, resulting in the formation of lactic acid:
Mechanism :
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