Who among the following was not the Vice-President of India?

The correct answer is Option (4) → Sarojini Naidu

Sarojini Naidu, the poet and freedom fighter known as the “Nightingale of India”, was the first woman Governor of an Indian state (United Provinces, 1947–49); she was never Vice-President.

The other three all served as Vice-President of India: V. V. Giri (1967–69), B. D. Jatti (1974–79) and K. R. Narayanan (1992–97); Giri and Narayanan later became President.