Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: Coordination Compounds

Question:

The complex $[Co(NH_3)_4(NO_2)_2]Cl$ will show.........

(A) Linkage isomerism
(B) lonization isomerism
(C) Coordination isomerism
(D) Geometrical isomerism

Choose the correct answer from the options given below:

Options:

(A), (B) and (D) only

(A), (B) and (C) only

(A), (B), (C) and (D)

(B), (C) and (D) only

Correct Answer:

(A), (B) and (D) only

Explanation:

The correct answer is Option (1) → (A), (B) and (D) only

Why (brief):

  • (A) Linkage isomerism: NO₂ can bind through N (nitro) or O (nitrito) → linkage isomers.
  • (B) Ionization isomerism: a coordinated NO₂⁻ can swap with the counter Cl⁻ to give an ionization isomer (e.g. $[Co(NH_3)_4(NO_2)Cl]NO_2$​).
  • (D) Geometrical isomerism: in an octahedral $[Co(NH_3)_4(NO_2)_2]^+$ the two identical NO₂ ligands can be cis or trans.

(C) Coordination isomerism does not apply (requires more than one metal center / both cationic and anionic complex parts).