The correct answer is option 2. 3 g.
The formula you provided is the correct expression for the ratio of the lowering of vapor pressure for two different solutes in the same solvent.
\( \frac{{P_0 - P_s}}{{P_0}} = \frac{{n_2}}{{n_1}} = \frac{{w_2M_1}}{{w_1M_2}} \)
Where: \( P_0 \) is the vapor pressure of the pure solvent, \( P_s \) is the vapor pressure of the solution, \( n_1 \) and \( n_2 \) are the number of moles of solute, \( w_1 \) and \( w_2 \) are the masses of solute, and \( M_1 \) and \( M_2 \) are the molar masses of solute.
We are given that the lowering of vapor pressure is the same for both cases.
For the first case, we have 1 g of urea (\( M_1 = 60 \, \text{g/mol} \)) dissolved in 50 g of water (\( w_1 = 50 \, \text{g} \)).
For the second case, we have an unknown mass of glucose (\( M_2 = 180 \, \text{g/mol} \)) dissolved in 50 g of water (\( w_2 = ? \)).
Using the given information and the formula, we can set up the equation:
\(\left(\frac{w_2M_1}{w_1M_2}\right)_{glucose} = \left(\frac{w_2M_1}{w_1M_2}\right)_{urea}\)
\( \frac{{1 \times 18}}{{50 \times 60}} = \frac{{w_2 \times 180}}{{50 \times 1}} \)
Simplifying the equation, we find:
\( w_2 = 3 \, \text{g} \)
Therefore, the mass of glucose that should be dissolved in 50 g of water to produce the same lowering of vapor pressure as 1 g of urea is 3 g, which corresponds to option (2). |