If the solution of the CuSO4 in which copper rod is immersed is diluted to 10 times, the electrode reduction potential (T = 298 K):
Answer & explanation
Correct answer: option 2
\(Cu^{2+} + 2e^− \rightarrow Cu\)
\(E_{cell} = E^o_{cell} − \frac{0.0591}{2} log\frac{1}{[Cu^{2+}]}\)
The new concentration of \(Cu^{2+}\) is \(\frac{1}{10}\) of \(Cu^{2+}\)
\(E^1_{cell} = E^o_{cell} − \frac{0.0591}{2}log\frac{10}{[Cu^{2+}]}\)
or, \(E^1_{cell} = E^o_{cell} − \frac{0.0591}{2}log\frac{1}{[Cu^{2+}]} − \frac{0.0591}{2}log 10\)
or, \(\Delta E_{cell} = −\frac{0.0591}{2}log10\)
or, \(\Delta E_{cell} = −\frac{0.059}{2}\)
Thus the electrode potential decreases by \(\frac{0.059 V}{2} = 0.03V\)