Practicing Success
Identify the correct products formed during the oxidizing reaction of permanganate ion with sulphite ion in acidic solution A. \(2OH^-\) B. \(2Mn^{2+}\) C. \(3H_2O\) D. \(MnO_2\) E. \(5SO_4^{2-}\) Choose the correct answer from the option given below: |
D, A and C only D, C and E only B, C and E only B, A and D only |
B, C and E only |
The correct answer is option 3. B, C and E only. Let us break down the reaction and the products formed during the oxidizing reaction of permanganate ion (\(MnO_4^-\)) with sulfite ion (\(SO_3^{2-}\)) in acidic solution. The balanced chemical equation for the reaction is: \[ \text{2MnO}_4^- + \text{5SO}_3^{2-} + \text{6H}^+ \rightarrow \text{2Mn}^{2+} + \text{5SO}_4^{2-} + \text{3H}_2\text{O} \] In this reaction: Permanganate ion (\(MnO_4^-\)) acts as the oxidizing agent. Sulphite ion (\(SO_3^{2-}\)) acts as the reducing agent. The reaction takes place in acidic solution, so there are \(H^+\) ions present. Here's what happens: 1. Permanganate ion oxidizes sulphite ion to sulfate ion. \[ \text{MnO}_4^- + \text{SO}_3^{2-} \rightarrow \text{Mn}^{2+} + \text{SO}_4^{2-} \] In this step, manganese in permanganate ion changes from \(+7\) oxidation state to \(+2\) oxidation state, while sulfur in sulfite ion changes from \(+4\) oxidation state to \(+6\) oxidation state. \[ \text{H}_3\text{O}^+ + \text{SO}_3^{2-} \rightarrow \text{H}_2\text{O} + \text{HSO}_3^- \] This step involves the acid-base reaction between hydronium ions (\(H_3O^+\)) and sulfite ions (\(SO_3^{2-}\)), leading to the formation of water (\(H_2O\)) and bisulfite ion (\(HSO_3^-\)). So, the correct products formed during the reaction are: \(2\) \(Mn^{2+}\) \(3\) \(H_2O\) \(5\) \(SO_4^{2-}\) This matches with option 3: \(B\), \(C\), and \(E\) only. |