Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Chemical Kinetics

Question:

For a chemical reaction:

A + B → Products

Experiment [A] mol L-1 [B] mol L-1 Initial rate mol L-1 s-1
1. 0.1 0.1 2.0 x 10-3
2 0.2 0.2 4.0 x 10-3
3. 0.1 0.2 2.0 x 10-3

What is the overall order of the reaction?

Options:

3

1

2

0

Correct Answer:

1

Explanation:

For a chemical reaction:

A + B → Products

Rate = k [A]x [B]y

2.0 x 10-3 = k [0.1]x [0.1]....(i)

4.0 x 10-3 = k [0.2]x [0.2]y  ....(ii)

2.0 x 10-3 = k [0.1]x [0.2]  .....(iii)

Dividing (ii) by (iii), we get

\(\frac{4.0 × 10^{-3}}{2.0 × 10^{-3}}\) = 2x

21 = 2x

x = 1

Dividing (iii) by (i), we get

\(\frac{2.0 × 10^{-3}}{2.0 × 10^{-3}}\) = 2y

20 = 2

y = 0

Rate = k [A]1 [B]0 

Overall order = 1 + 0 = 1