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Home/Practice questions/Chemistry
ChemistryOrganic: Amines

When a primary amine reacts with CHCl_3 in presence of ethanolic KOH…

When a primary amine reacts with \(CHCl_3\) in presence of ethanolic \(KOH\) to produce a foul smelling compound, the reaction is called:

Answer & explanation+

Correct answer: option 4

The correct answer is Option (4) → Carbylamine test

A primary amine heated with chloroform and ethanolic KOH gives a foul-smelling isocyanide; this is the carbylamine (isocyanide) test for primary amines:

    \( \ce{R-NH2 + CHCl3 + 3KOH} \xrightarrow{\Delta} \ce{R-NC + 3KCl + 3H2O} \)

NCERT (2026-27 edition):
Carbylamine Reaction

Textbook extract

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