Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Alcohols, Phenols and Ethers

Question:

An organic compound 'A' with molecular formula CH4O reacts with HI to give an alkyl iodide which than reacts with potassium cyanide to produce 'B'. Compound 'B' on reduction followed by reaction with HNO2 gives an alcohol which on oxidation gives 'C'. Compound 'C' on oxidation followed by reaction with CH3MgBr gives 'D' which on hydrolysis gives compound 'E' which is also an alcohol. 

Which of the following is a method of preparation of HNO2?

Options:

HCl+NaNO2

HNO3+OH-

HCl or H2SO4  + NaNO2

None of them 

Correct Answer:

HCl or H2SO4  + NaNO2

Explanation:

Here, the correct answer will be HCl or H2SO4  + NaNO

HNO2 i.e., nitrous acid can be prepared by the action of dilute HCl or H2SO4 on NaNO2 or any other nitrite.