Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Surface Chemistry

Question:

Case: read the passage and answer the following questions

There are mainly two types of adsorption of gases on solids. If accumulation of gas on the surface of a solid occurs on account of weak van der Waals’ forces, the adsorption is termed as physical adsorption or physisorption. When the gas molecules or atoms are held to the solid surface by chemical bonds, the adsorption is termed chemical adsorption or chemisorption. The chemical bonds may be covalent or ionic in nature. Chemisorption involves high energy of activation and is, therefore, often referred to as activated adsorption. Sometimes these two processes occur simultaneously and it is not easy to ascertain the type of adsorption.

Which of the following is not a favorable condition for physisorption?
Options:
High temperature
High pressure
Negative enthalpy
The higher critical temperature of adsorbate
Correct Answer:
High temperature
Explanation:
Since the enthalpy is low for physisorption Low temperature is favorable for adsorption. It decreases with the increase in temperature.