Read the Passage carefully and answer the questions. The carbonyl group of aldehydes and ketones is highly polar. The positively charged carbon is readily attacked by electron-rich nucleophile and the negatively charged oxygen atom is attacked by an electro-deficient electrophile. Aldehydes and ketones undergo nucleophilic addition reactions in the presence of acid or a base. The mechanism involves attack of a nucleophile on the electron deficient carbonyl carbon to form a tetrahedral intermediate. A new bond is formed between the carbon and oxygen. Protonation of the anion furnished by the reaction medium yields a neutral addition product. The addition product is same whether the reaction is catalyzed by acid or a base. For example in the presence of base aldehydes and ketones react with hydrogen cyanide to form cyanohydrin. |
The source of nucleophile in the base catalyzed cyanohydrin formation is |
HCN KCN NaCN $CH_3CN$ |
KCN |
The correct answer is Option (2) → KCN ** In base-catalyzed cyanohydrin formation, the nucleophile is the cyanide ion (CN⁻), which attacks the electrophilic carbonyl carbon.
|