Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Aldehydes, Ketones and Carboxylic Acids

Question:

Read the Passage carefully and answer the questions.

The carbonyl group of aldehydes and ketones is highly polar. The positively charged carbon is readily attacked by electron-rich nucleophile and the negatively charged oxygen atom is attacked by an electro-deficient electrophile. Aldehydes and ketones undergo nucleophilic addition reactions in the presence of acid or a base. The mechanism involves attack of a nucleophile on the electron deficient carbonyl carbon to form a tetrahedral intermediate. A new bond is formed between the carbon and oxygen. Protonation of the anion furnished by the reaction medium yields a neutral addition product. The addition product is same whether the reaction is catalyzed by acid or a base. For example in the presence of base aldehydes and ketones react with hydrogen cyanide to form cyanohydrin.

The source of nucleophile in the base catalyzed cyanohydrin formation is

Options:

HCN

KCN

NaCN

$CH_3CN$

Correct Answer:

KCN

Explanation:

The correct answer is Option (2) → KCN **

In base-catalyzed cyanohydrin formation, the nucleophile is the cyanide ion (CN⁻), which attacks the electrophilic carbonyl carbon.

  • KCN or NaCN provides the CN⁻ ion in solution.
  • HCN is the source of cyanide under acidic or neutral conditions, but in base-catalyzed reactions, the cyanide ion comes from the salt.