The plot of Ink and 1/T is given in the figure what is its slope? |
-Ea/R Ea/R Ea/2.303R -Ea/2.303R |
-Ea/R |
The correct answer is option 1. \(-\frac{E_a}{R}\). The Arrhenius equation describes the temperature dependence of reaction rates. It states that the rate constant (\(k\)) of a reaction is exponentially related to the inverse of the temperature (\(T\)): \(k = Ae^{-\frac{E_a}{RT}} \) Where: \( A \) is the pre-exponential factor, which represents the frequency of collisions between reactant molecules. \( E_a \) is the activation energy, which represents the minimum energy required for a reaction to occur. \( R \) is the gas constant. \( T \) is the absolute temperature in Kelvin. Taking the natural logarithm of both sides of the equation, we get: \( \ln(k) = \ln(A) - \frac{E_a}{RT} \) This equation has the form of a straight line equation, \(y = mx + c\), where: \( y = \ln(k) \), \( m = -\frac{E_a}{R} \), \( x = \frac{1}{T} \), and \( c = \ln(A) \). So, when we plot \(\ln(k)\) against \(\frac{1}{T}\), we should get a straight line with slope \(m = -\frac{E_a}{R}\). This slope represents the ratio of activation energy to the gas constant (\(R\)). Hence, the correct option is: 1. \(-\frac{E_a}{R}\) This relationship is fundamental in understanding how temperature affects reaction rates and is often used in kinetics studies to determine activation energies. |