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Home/Practice questions/Chemistry
ChemistryPhysical: Electro Chemistry

Match List-I with List-IIList-IPropertyList-IIUnit(A) Conductivity(I)…

Match List-I with List-II

List-I
Property
List-II
Unit
(A) Conductivity(I) S m-1
(B) Molar conductivity(II) ohm m
(C) Resistivity(III) S
(D) Conductance(IV) S m2 mol-1

Choose the correct answer from the options given below:

Answer & explanation+

Correct answer: option 2

The correct answer is Option (2) → (A) - (I), (B) - (IV), (C) - (II), (D) - (III)

All four quantities come from the resistance of a conductor, R = ρ l/A, where l is the length and A the area of cross-section. Their units follow directly from their definitions:

  • (A) Conductivity — This matches (I) S m-1. Conductivity (κ) is the reciprocal of resistivity.

        \( \displaystyle \kappa=\frac{1}{\rho}=\frac{1}{\Omega\,\mathrm{m}}=\mathrm{S\,m^{-1}} \)

  • (B) Molar conductivity — This matches (IV) S m2 mol-1. Molar conductivity is conductivity divided by the molar concentration (in mol m−3).

        \( \displaystyle \Lambda_m=\frac{\kappa}{c}=\frac{\mathrm{S\,m^{-1}}}{\mathrm{mol\,m^{-3}}}=\mathrm{S\,m^{2}\,mol^{-1}} \)

  • (C) Resistivity — This matches (II) ohm m. Rearranging the resistance equation gives the unit of resistivity.

        \( \displaystyle \rho=\frac{R\,A}{l}=\frac{\Omega\times\mathrm{m^{2}}}{\mathrm{m}}=\Omega\,\mathrm{m} \)

  • (D) Conductance — This matches (III) S. Conductance is the reciprocal of resistance, and its unit ohm−1 is called the siemens.

        \( \displaystyle G=\frac{1}{R}=\Omega^{-1}=\mathrm{S} \)

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