Match List I with List II
| List I | List II |
| A. Cu | I. +3 |
| B. Sc | II. +7 |
| C. Mn | III. +2 |
| D. Fe | IV. +1 |
Choose the correct answer from the options given below:
Answer & explanation
Correct answer: option 2
The correct answer is option 2. A-IV, B-I, C-II, D-III.
| List I | List II |
| A. Cu | IV. +1 |
| B. Sc | I. +3 |
| C. Mn | II. +7 |
| D. Fe | III. +2 |
Let us go through each element in List I and explain their common oxidation states to match them with List II.
A.Copper (Cu)
Copper can exist in two common oxidation states:
+1: In compounds like copper(I) chloride (CuCl) and copper(I) oxide (Cu₂O), copper exhibits a +1 oxidation state.
+2: This is another common oxidation state, seen in compounds like copper(II) sulfate (CuSO₄).
However, in this question, we are looking for the +1 oxidation state for copper. This corresponds to IV in List II.
B. Scandium (Sc)
Scandium almost exclusively exhibits an oxidation state of +3 in all of its compounds. This is because scandium has a valence electron configuration of \( [Ar] 3d^1 4s^2 \). When it loses all three valence electrons, it achieves a stable noble gas configuration. Therefore, scandium is almost always found in the +3 oxidation state.
Examples:
Scandium chloride (ScCl₃)
Scandium oxide (Sc₂O₃)
Thus, +3 oxidation state corresponds to I in List II.
C. Manganese (Mn)
Manganese is a transition metal that can exhibit a wide range of oxidation states, including:
+2: Common in manganese(II) chloride (MnCl₂)
+4: Found in manganese dioxide (MnO₂)
+7: The highest oxidation state, found in compounds like potassium permanganate (KMnO₄).
In the +7 oxidation state, manganese is highly oxidizing, such as in the permanganate ion \( \text{MnO}_4^- \).
So, for this question, the +7 oxidation state corresponds to II in List II.
D. Iron (Fe)
Iron commonly exhibits two oxidation states:
+2: This occurs in compounds like iron(II) chloride (FeCl₂), where iron has lost two electrons.
+3: In compounds like iron(III) chloride (FeCl₃), iron has lost three electrons.
In this case, we are asked to find the +2 oxidation state, which corresponds to III in List II.