In Etard reaction, the final product is
Answer & explanation
Correct answer: option 1
The correct answer is Option (1) → Aromatic aldehyde
Strong oxidising agents oxidise toluene all the way to benzoic acid. The oxidation can be stopped at the aldehyde stage with a reagent that converts the methyl group into an intermediate that is hard to oxidise further. In the Etard reaction, toluene is treated with chromyl chloride, \( \ce{CrO2Cl2} \), in \( \ce{CS2} \). The methyl group is oxidised to a chromium complex, which on hydrolysis gives benzaldehyde.
So the final product of the Etard reaction is an aromatic aldehyde.
NCERT (2026-27 edition):
Use of Chromyl Chloride (CrO2Cl2)
