Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Aldehydes, Ketones and Carboxylic Acids

Question:

In Etard reaction, the final product is

Options:

Aromatic aldehyde

Aromatic chloride

Aromatic amine

Aromatic alcohol

Correct Answer:

Aromatic aldehyde

Explanation:

The correct answer is option 1. Aromatic aldehyde.

The reaction begins with an alkene – allylic hydrogen reaction with chromyl chloride, forming a precipitate called the Etard complex. This Etard complex is then decomposed with the help of a reducing environment to prevent its oxidation into a carboxylic acid. This reducing environment is generally provided by a saturated solution of aqueous sodium sulphite. Carbon tetrachloride is the most commonly used solvent for this method but carbon disulfide and chloroform can also be used as solvents. Aldehyde product of high purity can be obtained by purifying the Etard complex before its decomposition (so that its reaction with the unreacted reagent is prevented). The time frame for this equation may vary from a few days to several weeks but the yields are relatively high.

Mechanism :