Among the following series of transition metal ions, the one where all metal ions have 3d2 electronic configuration is:
Answer & explanation
Correct answer: option 2
The correct answer is (2), $Ti^{2+}, V{3+}, Cr^{4+}, \text{ and } Mn^{5+}$ because these ions all have a \(3d^2\) electronic configuration.
The 3d orbital can hold up to 10 electrons. The ions in the series $Ti^{2+}, V{3+}, Cr^{4+},\text{ and } Mn^{5+}$ have 2 electrons in the 3d orbital, so this is the only series where all the ions have a 3d2 electronic configuration.
The other series in question have different numbers of electrons in the 3d orbital. For example, \(Ti^+\) has 1 electrons in the 3d orbital, \(V^{4+}\) has 1 electron in the 3d orbital, \(Cr^{6+}\) has 0 electrons in the 3d orbital, and Mn7+ has 0 electron in the 3d orbital.
Here is a table of the electronic configurations of the ions in question:
|
Ion |
Electronic Configuration |
|
Ti+ |
[Ar] 4s1 3d1 |
|
V4+ |
[Ar] 4s0 3d1 |
|
Cr6+ |
[Ar] 4s0 3d0 |
|
Mn7+ |
[Ar] 4s0 3d0 |
|
Ti2+ |
[Ar] 4s0 3d2 |
|
V3+ |
[Ar] 4s0 3d2 |
|
Cr4+ |
[Ar] 4s0 3d2 |
|
Mn5+ |
[Ar] 4s0 3d2 |
As you can see, the only ions with a \(3d^2\) electronic configuration are $Ti^{2+}, V{3+}, Cr^{4+},\text{ and } Mn^{5+}$. This is why the answer is (2) $Ti^{2+}, V{3+}, Cr^{4+},\text{ and } Mn^{5+}$.