Product (A) is: |
\(C_6H_5NO_2\) \(C_6H_5OH\) \(m-NO_2C_6H_5-NH_2\) \(C_6H_5NH_2\) |
\(C_6H_5OH\) |
The correct answer is option 2. \(C_6H_5OH\). To identify the product \(A\) of the given reaction sequence, we need to understand each step: Given Reaction Sequence: \(C_6H_5NO_2 \underset{\underset{3. H_2O}{2. HNO_2}}{\overset{1. Fe/HCl}{\longrightarrow}} A\)) Here is how to interpret each step Reduction with Fe/HCl:
The nitro group (\(-NO_2\)) in \(C_6H_5NO_2\) (nitrobenzene) is reduced to an amine group (\(-NH_2\)) using iron and hydrochloric acid. This step converts nitrobenzene to aniline (\(C_6H_5NH_2\)). Diazotization with \(HNO_2\) (Nitrous acid):
Aniline (\(C_6H_5NH_2\)) is treated with nitrous acid (\(HNO_2\)) at a low temperature (0–5°C) to form a diazonium salt. The diazotization of aniline produces phenyl diazonium chloride (\(C_6H_5N_2^+ Cl^-\)). Hydrolysis with \(H_2O\):
The diazonium salt is hydrolyzed with water, which converts the diazonium group into a hydroxyl group. The hydrolysis of phenyl diazonium chloride results in phenol (\(C_6H_5OH\)). So, the correct answer is phenol. |