Which one of the following statements is correct with reference to the solubility of gases in liquid?
Answer & explanation
Correct answer: option 1
The correct answer is Option (1) → The solubility of gases in liquids increases with the increase of pressure.
- The solubility of gases in liquids follows Henry’s Law, which states that:
- At constant temperature, the solubility of a gas in a liquid is directly proportional to the partial pressure of the gas above the liquid.
- Mathematically: p = KH × x
- Where p = partial pressure of the gas
- x = mole fraction of the gas in the solution
- KH = Henry’s law constant
- Thus, when pressure increases, more gas dissolves in the liquid, increasing solubility.
- Temperature also affects solubility. Generally, solubility of gases decreases with increase in temperature because gases escape from solution when heated.
Option 1 The solubility of gases in liquids increases with the increase of pressure. Correct.
According to Henry’s law, solubility increases with increasing pressure.
Option 2 The solubility of gases in liquids is not affected with the increase of temperature. Incorrect. Temperature significantly affects gas solubility.
Option 3 The solubility of gases in liquids increases with the increase of temperature. Incorrect.
In most cases, gas solubility decreases when temperature increases.
Option 4 At high altitude, the partial vapour pressure of O₂ becomes greater than that at the sea level. Incorrect.
At high altitude, atmospheric pressure is lower, so the partial pressure of oxygen is also lower.