Which of the following reactions will give n-Propanol as a product? (A) Hydroboration oxidation of Propene Choose the correct answer from the options given below: |
(A), (B) and (D) only (A), (B) and (C) only (A), (B), (C) and (D) (A), (C) and (D) only |
(A), (B) and (C) only |
The correct answer is Option (2) → (A), (B) and (C) only n-Propanol ($CH_{3}CH_{2}CH_{2}OH$) is a primary alcohol. Each reaction must be checked to see whether it forms this compound. Analysis of the Statements (A) Hydroboration–oxidation of propene Hydroboration–oxidation proceeds through anti-Markovnikov addition, where the $OH$ group attaches to the less substituted carbon of the double bond. Reaction: $CH_{3}-CH=CH_{2} \rightarrow CH_{3}-CH_{2}-CH_{2}OH$ Product formed: n-Propanol Thus, statement (A) is correct. (B) Reduction of propanal Propanal is an aldehyde. Reduction of aldehydes using hydrogen with catalysts such as Pd, Pt, or Ni converts them into primary alcohols. Reaction: $CH_3CH_2CHO \rightarrow CH_3CH_2CH_2OH$ Product formed: n-Propanol Thus, statement (B) is correct. (C) Reaction of formaldehyde with ethylmagnesium bromide Grignard reagents react with formaldehyde to produce primary alcohols with one additional carbon atom. Reaction: $HCHO + C_2H_5MgBr \rightarrow CH_3CH_2CH_2OH$ (after hydrolysis) Product formed: n-Propanol Thus, statement (C) is correct. (D) Acid catalyzed hydration of propene Acid-catalyzed hydration follows Markovnikov addition. The OH group attaches to the more substituted carbon, producing: $CH_3-CHOH-CH_3$ Product formed: 2-propanol, not n-propanol. Thus, statement (D) is incorrect. |