Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Electro Chemistry

Question:

A zinc rod is dipped in 0.1 M solution of ZnSO4. The salt is 95% dissociated at this dilution at 298 K. What is the electrode potential?
[E°Zn2+/Zn = – 0.76 V] [log95 = 1.9777]

Options:

0.79 V

-0.79 V

0.69 V

-0.69 V

Correct Answer:

-0.79 V

Explanation:

The electrode reaction is given as
Zn+2 + 2e- → Zn 
Using Nernst Equation

EZn2+/Zn = E°Zn2+/Zn - \(\frac{0.0591}{2}\)log\(\frac{1}{[Zn^{2+}]}\) 

[Zn2+] = \(\frac{95}{100}\)x0.1 = 0.095

EZn2+/Zn = -0.76 - 0.0295log\(\frac{1}{[0.095]}\) 

EZn2+/Zn = -0.76 - 0.0295[log1000 - log95]

EZn2+/Zn = -0.76 - 0.0295[3 - 1.9777]

EZn2+/Zn = -0.76 - 0.03016 = -0.79 V