Practicing Success
A zinc rod is dipped in 0.1 M solution of ZnSO4. The salt is 95% dissociated at this dilution at 298 K. What is the electrode potential? |
0.79 V -0.79 V 0.69 V -0.69 V |
-0.79 V |
The electrode reaction is given as EZn2+/Zn = E°Zn2+/Zn - \(\frac{0.0591}{2}\)log\(\frac{1}{[Zn^{2+}]}\) [Zn2+] = \(\frac{95}{100}\)x0.1 = 0.095 EZn2+/Zn = -0.76 - 0.0295log\(\frac{1}{[0.095]}\) EZn2+/Zn = -0.76 - 0.0295[log1000 - log95] EZn2+/Zn = -0.76 - 0.0295[3 - 1.9777] EZn2+/Zn = -0.76 - 0.03016 = -0.79 V |