Following reaction takes place in Daniell cell: \(Zn(s) + Cu^{2+}(aq) \longrightarrow Zn^{2+} (aq) + Cu(s); \) \(E^o_{cell} = 1.1 V\) Standard Gibbs energy in this case will be: |
\(-2123.0 kJ/mol\) \(-212.3 kJ/mol\) \(+212.3 kJ/mol\) \(+21227 kJ/mol\) |
\(-212.3 kJ/mol\) |
The correct answer is option 2. \(-212.3 kJ/mol\). The given reaction is \(Zn(s) + Cu^{2+}(aq) \longrightarrow Zn^{2+} (aq) + Cu(s)\) From the reaction, \(n = 2\) Given, \(E^o_{cell} = 1.1 V\) \(F = 96500 C\) Gibbs Free Energy, \(\Delta G^o = -nFE^o_{cell}\) or, \(\Delta G^o = - 2 × 96500 × 1.1\) or, \(\Delta G^o = -212300 J\) or, \(\Delta G^o = -212.3 kJ/mol\) |