Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Chemical Kinetics

Question:

Consider the following reaction; A + B → C

Experiment Initial [A] Initial [B] Rate of formation of C (m/s)
1 0.10 M 1.0 M 2.1 x 10-3
2 0.20 M 1.0 M 8.4 x 10-3 
3 0.20 M 2.0 M 8.4 x 10-3

What is the order of reaction with respect to A and B?

Options:

2,0

0,2

2,1

1,2

Correct Answer:

2,0

Explanation:

r = k[A]x[B]

2.1 x 10-3 = k[0.1]x[1]y          ......(i)

8.4 x 10-3 = k[0.2]x[1]y          ......(ii)

8.4 x 10-3 = k[0.2]x[2]y          ......(iii)

Dividing equation (ii) by (i)

\(\frac{8.4 × 10^{-3}}{2.1 × 10^{-3}}\) = \(\frac{k[0.2]^x[1]^y}{k[0.1]^x[1]^y}\)

4 = 2

22 = 2

x = 2

Dividing equation (iii) by (ii)

\(\frac{8.4 × 10^{-3}}{8.4 × 10^{-3}}\) = \(\frac{k[0.2]^x[2]^y}{k[0.2]^x[1]^y}\)

1 = 2

20 = 2

y = 0

r = k[A]2[B]0