Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Solutions

Question:

Based on the solute solvent interactions, arrange the following in the order of increasing solubility in n-octane.

A. Cyclohexane

B. KCl

C. CH3OH

D. CH3NH2

E. CH3CN

Choose the correct answer from the options given below:

Options:

A < B < C < D < E

B < C < E < D < A

C < B < A < E < D

B < C < D < E < A

Correct Answer:

B < C < E < D < A

Explanation:

n-Octane is nonpolar and can dissolve non-polar solutes. It cannot dissolve polar (and ionic) solutes.

Cyclohexane is non-polar. Hence, easily soluble in n-octane.

Methyl amine is less polar than acetonitrile (CH3CN).

Methanol and acetonitrile are polar and have very low solubility in n-octane.

KCl is ionic compound and hence, insoluble in n-octane.

The increasing order for solubility in n-octane is as follows: KCl < CH3OH < CH3CN < CH3NH2 < Cyclohexane i.e., B < C < E < D < A.