Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Aldehydes, Ketones and Carboxylic Acids

Question:

If the pKa value of acetic acid is 4.76, predict the pKa value of HCl.

Options:

-7

4.2

7

10

Correct Answer:

-7

Explanation:

The correct answer is option 1. \(-7\).

To predict the \(pK_a\) value of \(HCl\) given the pKa value of acetic acid \((CH_3COOH)\), we need to understand the concept of \(pK_a\) and its relationship to acid strength.

Understanding \(pK_a\):

\(pK_a\): This is the negative logarithm (base 10) of the acid dissociation constant \((K_a)\) of an acid in water. Lower \(pK_a\) values indicate stronger acids (acids that readily donate protons), while higher \(pK_a\) values indicate weaker acids.

Acetic Acid \((CH_3COOH)\): Its \(pK_a\) value is given as \(4.76\). This means acetic acid is a weak acid because it has a relatively higher \(pK_a\) value.

Predicting the \(pK_a\) of \(HCl\):

\(HCl\) (Hydrochloric Acid): \(HCl\) is a strong acid, which means it completely dissociates in water to produce \(H^+\) ions and \(Cl^-\) ions. Because it dissociates almost completely, its \(K_a\) value is very large, and consequently, its pKa value is very low.

Comparison to Acetic Acid: Since acetic acid (\(pK_a\) = 4.76) is a weak acid, \(HCl\), being a strong acid, will have a significantly lower \(pK_a\) value.

Conclusion:

Given that \(HCl\) is a strong acid, its \(pK_a\) value is far lower than that of acetic acid. It's reasonable to estimate that the \(pK_a\) value of \(HCl\) is close to \(0\) or even negative. So, the correct answer is option 1. \(-7\). This option suggests a very low \(pK_a\) value, which aligns with \(HCl\) being a strong acid compared to acetic acid.