Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Aldehydes, Ketones and Carboxylic Acids

Question:

Acetaldehyde reacts with hydrogen cyanide via. nucleophilic addition to give acetaldehyde cyanohydrin which then reacts with two moles of water and one mole of hydrochloric acid and than heated. What will be the final product of the reaction?   

Options:

Mandelic acid 

Lactic acid 

Tartaric acid 

None of the above 

Correct Answer:

Lactic acid 

Explanation:

The correct answer is option 2. Lactic acid.

When acetaldehyde (\( \text{CH}_3\text{CHO} \)) reacts with hydrogen cyanide (HCN) via nucleophilic addition, it forms acetaldehyde cyanohydrin (\( \text{CH}_3\text{CH(OH)CN} \)). Acetaldehyde cyanohydrin (\( \text{CH}_3\text{CH(OH)CN} \)) reacts with two moles of water (\( \text{H}_2\text{O} \)) and one mole of hydrochloric acid (\( \text{HCl} \)) under acidic conditions. This process is known as acid hydrolysis. Acid hydrolysis of acetaldehyde cyanohydrin (\( \text{CH}_3\text{CH(OH)CN} \)) typically results in the formation of lactic acid (\( \text{CH}_3\text{CH(OH)COOH} \)).



The final product of the reaction, after acid hydrolysis and heating, is **lactic acid** (\( \text{CH}_3\text{CH(OH)COOH} \)).