Arrange the following ligands in the increasing order of their field strength: (A) $en$ Choose the correct answer from the options given below: |
(C), (D), (B), (A) (A), (B), (D), (C) (A), (D), (B), (C) (C), (B), (D), (A) |
(C), (D), (B), (A) |
The correct answer is Option (1) → (C), (D), (B), (A) Ligand field strength generally follows a pattern based on the donor atom. The strength typically increases in the following order: Halides < Oxygen donors < Nitrogen donors < Carbon donors The field strength of ligands is determined using the spectrochemical series, which arranges ligands from weak field → strong field. Weak field ligands → small crystal field splitting (Δ) Strong field ligands → large crystal field splitting Relevant order from the spectrochemical series: S²⁻ < OH⁻ < en < stronger ligands (C) S²⁻ (D) OH⁻ (B) edta⁴⁻ (A) en (ethylenediamine) Increasing order of field strengthS²⁻ < OH⁻ < edta⁴⁻ < en The correct answer is Option (1) → (C), (D), (B), (A). |