Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Chemical Kinetics

Question:

The first order reaction is 20% complete in 10 minutes. What is the rate constant of the reaction?

Options:

0.223 min-1

0.0223 min-1

2.23 min-1

22.3 min-1

Correct Answer:

0.0223 min-1

Explanation:

For first order reaction, 

k = \(\frac{2.303}{t}\)log\(\frac{a}{a-x}\)

k = \(\frac{2.303}{10}\)log\(\frac{100}{80}\)

k = \(\frac{2.303}{10}\)log\(\frac{5}{4}\)

k = \(\frac{2.303}{10}\)(log5 - log4)

k = \(\frac{2.303}{10}\)(0.69 - 0.60)

k = \(\frac{2.303}{10}\) x 0.09

k ≈ 0.0223 min-1