Arrange the following compounds in increasing order of their reactivity towards nucleophilic addition reaction: (A) Ethanal Choose the correct answer from the options given below: |
(D), (C), (B), (A) (A), (B), (C), (D) (D), (C), (A), (B) (A), (B), (D), (C) |
(D), (C), (B), (A) |
The correct answer is Option (1) → (D), (C), (B), (A) Aldehydes are more reactive than ketones in nucleophilic addition reactions due to two main factors: electronic and steric effects. Electronically, the carbonyl carbon in an aldehyde is more positive because it is bonded to only one electron-donating alkyl group, compared to the two alkyl groups in a ketone. Sterically, the two alkyl groups on a ketone create more hindrance, making it more difficult for a nucleophile to attack the carbonyl carbon. Increasing Order (least reactive → most reactive): Butanone (more hindered ketone) (D) < Propanone (ketone) (C) < Propanal (B) < Ethanal (A) (less hindered aldehyde) |