Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Alcohols, Phenols and Ethers

Question:

Arrange the following compounds in the increasing order of their boiling points:

(A) Pentan-1-ol
(B) n-Butane
(C) Pentan-1-al
(D) Ethoxyethane

Choose the correct answer from the options given below:

Options:

(A), (B), (C), (D)

(A), (C), (B), (D)

(B), (D), (C), (A)

(B), (C), (D), (A)

Correct Answer:

(B), (D), (C), (A)

Explanation:

The correct answer is Option (3) → (B), (D), (C), (A)

Let’s analyze each compound:

  • (B) n-Butane → non-polar, only weak van der Waals forces → lowest b.p.
  • (D) Ethoxyethane (diethyl ether) → polar but no hydrogen bonding
  • (C) Pentan-1-al → polar, stronger dipole–dipole interactions
  • (A) Pentan-1-ol → hydrogen bonding → highest b.p.

Increasing order of boiling points:

$(B) < (D) < (C) < (A)$