Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Chemical Kinetics

Question:

Match List I with List II.

List I List II
A. Order of complex reaction is determined by I. Instanteous rate
B. Rate of zero-order reaction is equal to II. Rate Law
C. Relationship between rate of reaction and concentration of reactants III. Order of slowest step
D. Rate at a particular moment in time IV. Rate constant

Choose the correct answer from the options given below:

Options:

A-III, B-II, C-IV, D-I

A-III, B-IV, C-II, D-I

A-III, B-IV, C-I, D-II

A-II, B-III, C-IV, D-I

Correct Answer:

A-III, B-IV, C-II, D-I

Explanation:

A. Order of complex reaction is determined by Order of slowest step.

As complex reaction is a multistep reaction in which the rate of reaction will depend mostly on the slowest step. Hence, order of reaction is also determined by the slowest step.

B. Rate of zero order reaction is equal to Rate constant.

Consider a zero-order reaction, A → Products

Rate of reaction = k [A]0 = k (rate constant)

C. Relationship between rate of reaction and concentration of reactants is known as Rate Law. 

aA + bB → cC + dD

Rate law = k [A]m [B]n where m and n are respective order w.r.t A and B determined experimentally.

D. Rate at particular moment of time is known as Instanteous rate.

Rate = \(\frac{dC}{dt}\) 

where dC is small change in concentration in small time interval dt.