Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: Coordination Compounds

Question:

What is the CFSE for [FeF6]3-

Options:

0 Dq

-12 Dq

24 Dq

20 Dq

Correct Answer:

0 Dq

Explanation:

In [FeF6]3- 

x + 6(-1) = -3

x - 6 = -3

x = -3 + 6 = 3

26Fe : [Ar]4s23d6

Fe3+ : [Ar]3d5

Since F is a  weak ligand according to CFSE theory there will be 3 electrons in three t2g orbital and 2 electrons in two eg level.

So, CFSE = (-4 x 3)Dq + (+6 x 2)Dq = 0