Calculated value of magnetic moment (BM) of an aqueous solution of $Mn^{2+}$ is ......... |
5.92 4.90 3.87 2.84 |
5.92 |
The correct answer is Option (1) → 5.92 Electronic configuration of Mn²⁺ Atomic number of Mn = 25 Ground state configuration of Mn: Mn = [Ar] 3d⁵ 4s² When manganese forms Mn²⁺: Two electrons are removed from the 4s orbital. Mn²⁺ = [Ar] 3d⁵ Thus Mn²⁺ has: Number of unpaired electrons (n) = 5 Using the spin-only magnetic moment formula: $\mu = \sqrt{n(n+2)} \text{ BM}$ where μ = magnetic moment in Bohr Magneton (BM) n = number of unpaired electrons $\mu = \sqrt{5(5+2)} = \sqrt{35} \approx 5.92 \text{ BM}$ |