Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Solutions

Question:

William Henry made systematic studies of the solubility of a gas in a liquid. He gave a quantitative relationship between the solubility of a gas in a solvent and pressure which is known as Henry’s law. The law states that- the mass of a gas dissolved per unit volume of the solvent at a constant temperature is directly proportional to the pressure of the gas in equilibrium with the solution.

If m is the mass of the gas dissolved in a unit volume of the solvent and p is the pressure of the gas in equilibrium with the solution, then

\[m \propto p\]

\[or,  m = K.p\]

where K is the proportionality constant. The magnitude of K depends on the nature of the gas, the nature of the solvent, the temperature and the units of pressure. Thus, Henry’s law may also be stated as: the solubility of a gas in a liquid at a particular temperature is directly proportional to the pressure of the gas in equilibrium with the solution.

Henry's law constant is dependent on which of the following factors?

Options:

The nature of the solvent

The nature of the gas

Temperature & pressure

All of the above

Correct Answer:

All of the above

Explanation:

The answer is 4. All of the above.

The value of Henry's law constant of a gas is dependent on the following factors:

The nature of the solvent: The solvent-solute interactions affect the solubility of a gas in a liquid. Solvents with stronger intermolecular forces will have higher Henry's law constants for gases that have similar intermolecular forces.

The nature of the gas: The gas-solvent interactions also affect the solubility of a gas in a liquid. Gases with stronger intermolecular forces will have higher Henry's law constants for solvents with similar intermolecular forces.

Temperature: The temperature of the system affects the solubility of a gas in a liquid. As the temperature increases, the solubility of a gas in a liquid decreases. This is because the kinetic energy of the gas molecules increases, which makes it more likely for them to escape from the liquid.

Pressure: The pressure of the system affects the solubility of a gas in a liquid. As the pressure of a gas increases, the solubility of the gas in a liquid increases. This is because the increased pressure forces more gas molecules into the liquid.

Therefore, the value of Henry's law constant of a gas is dependent on all of the factors listed above.