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William Henry made systematic studies of the solubility of a gas in a liquid. He gave a quantitative relationship between the solubility of a gas in a solvent and pressure which is known as Henry’s law. The law states that- the mass of a gas dissolved per unit volume of the solvent at a constant temperature is directly proportional to the pressure of the gas in equilibrium with the solution. If m is the mass of the gas dissolved in a unit volume of the solvent and p is the pressure of the gas in equilibrium with the solution, then \[m \propto p\] \[or, m = K.p\] where K is the proportionality constant. The magnitude of K depends on the nature of the gas, the nature of the solvent, the temperature and the units of pressure. Thus, Henry’s law may also be stated as: the solubility of a gas in a liquid at a particular temperature is directly proportional to the pressure of the gas in equilibrium with the solution. |
Henry's law constant is dependent on which of the following factors? |
The nature of the solvent The nature of the gas Temperature & pressure All of the above |
All of the above |
The answer is 4. All of the above. The value of Henry's law constant of a gas is dependent on the following factors: The nature of the solvent: The solvent-solute interactions affect the solubility of a gas in a liquid. Solvents with stronger intermolecular forces will have higher Henry's law constants for gases that have similar intermolecular forces. The nature of the gas: The gas-solvent interactions also affect the solubility of a gas in a liquid. Gases with stronger intermolecular forces will have higher Henry's law constants for solvents with similar intermolecular forces. Temperature: The temperature of the system affects the solubility of a gas in a liquid. As the temperature increases, the solubility of a gas in a liquid decreases. This is because the kinetic energy of the gas molecules increases, which makes it more likely for them to escape from the liquid. Pressure: The pressure of the system affects the solubility of a gas in a liquid. As the pressure of a gas increases, the solubility of the gas in a liquid increases. This is because the increased pressure forces more gas molecules into the liquid. Therefore, the value of Henry's law constant of a gas is dependent on all of the factors listed above. |