Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: Coordination Compounds

Question:

Select the correct combination of coordination number and type of hybridization, respectively, in "trigonal bipyramidal" complex.

Options:

4 and $sp^3d$

5 and $sp^3d$

5 and $dsp^3$

4 and $dsp^2$

Correct Answer:

5 and $sp^3d$

Explanation:

The correct answer is Option (2) → 5 and $sp^3d$
A trigonal bipyramidal complex has coordination number 5 and sp³d hybridization.

  • Trigonal bipyramidal geometry involves five ligand positions around the central atom → coordination number = 5.

  • To accommodate five electron pairs, the central atom undergoes sp³d hybridization (one s, three p, and one d orbital).

  • Hybridization dsp³ is used for different geometries like square pyramidal or trigonal bipyramidal in some valence bond descriptions, but in standard coordination chemistry for trigonal bipyramidal complexes, it is written as sp³d.