Practicing Success
For the thermal rearrangement of vinyl allyl ether (g) to allyl acetaldehyde (g) at 175°C, \(A = 5 × 10^{11} exp^{(–128000/RT)}\), where K is in s–1 and activation energy in J mol–1. The enthalpy of activation in kJ mol–1 is: |
224.3 142.3 12.43 124.3 |
124.3 |
The correct answer is option 4. 124.3. Given, \(A = 5 × 10^{11} exp^{(–128000/RT)}\) \(A = 5 × 10^{11} exp^{(–E_a/RT)}\) \(E_a = 128000 \text{ J mol}^{-1}\) For Gaseous reaction, Her, \(\Delta \eta\) is change in the number of molecules, when So, \(\Delta H = 128000 − 8.314 × 448 \text{ J mol}^{-1}\) \( = (128000 − 3725) \text{ J mol}^{−1}\) \( = 124275 \text{ J mol}^{−1}\) \( = 124.3 \text{ kJ mol}^{−1}\) |