The correct answer is Option (1) → $COCH_3$
Iodoform test is positive for compounds that have:
- CH₃–CO– (methyl ketone group) → e.g., acetaldehyde, acetone, acetophenone
- CH₃–CH(OH)– (methyl carbinol group) → e.g., ethanol, secondary alcohols with CH₃CH(OH)– structure
These give yellow precipitate of CHI₃ (iodoform) with I₂ + NaOH (or I₂ + base).
Why others are wrong:
- COO⁻ (carboxylate): No iodoform test
- CHO (aldehyde): Only acetaldehyde (CH₃CHO) gives it because it has CH₃CO– structure; other aldehydes don’t
- OH (alcohol): Only specific ones like ethanol, not all alcohols
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