Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: Coordination Compounds

Question:

Which of the following is the correct order of the strength of \(\pi \)-acceptor ligands?

Options:

CN < RNC < CO < NO+

CO < NO+ < CN< RNC

RNC < NO+ < CN < CO

NO+ < CO < CN < RNC

Correct Answer:

CN < RNC < CO < NO+

Explanation:

The correct answer is option (1) CN < RNC < CO < NO+.

The strength of a \(\pi \)-acceptor ligand is determined by the electronegativity of the ligand. The more electronegative the ligand, the stronger the pi-acceptor.

In the list of ligands given, CN is the most electronegative, followed by RNC, CO, and NO+. Therefore, the order of pi-acceptor strength is CN < RNC < CO < NO+.

The explanation for the order is as follows:

CN is the most electronegative ligand because it has a negative charge, which attracts electrons to the ligand.

RNC is less electronegative than CN because it has a triple bond, which makes the electrons more localized.

CO is less electronegative than RNC because it has a double bond, which makes the electrons more delocalized.

NO+ is the least electronegative ligand because it has a positive charge, which pulls electrons away from the ligand.

Therefore, the order of \(\pi \)-acceptor strength is CN < RNC < CO < NO+.