Which of the following is the correct order of the strength of \(\pi \)-acceptor ligands? |
CN− < RNC < CO < NO+ CO < NO+ < CN− < RNC RNC < NO+ < CN− < CO NO+ < CO < CN− < RNC |
CN− < RNC < CO < NO+ |
The correct answer is option (1) CN− < RNC < CO < NO+. The strength of a \(\pi \)-acceptor ligand is determined by the electronegativity of the ligand. The more electronegative the ligand, the stronger the pi-acceptor. In the list of ligands given, CN− is the most electronegative, followed by RNC, CO, and NO+. Therefore, the order of pi-acceptor strength is CN− < RNC < CO < NO+. The explanation for the order is as follows: CN− is the most electronegative ligand because it has a negative charge, which attracts electrons to the ligand. RNC is less electronegative than CN− because it has a triple bond, which makes the electrons more localized. CO is less electronegative than RNC because it has a double bond, which makes the electrons more delocalized. NO+ is the least electronegative ligand because it has a positive charge, which pulls electrons away from the ligand. Therefore, the order of \(\pi \)-acceptor strength is CN− < RNC < CO < NO+. |