Which of the following compounds will give Fehling's solution test? (A) $CH_3CHO$ |
(A), (B) and (D) only (A), (C) and (D) only (A), (B), (C) and (D) (B), (C) and (D) only |
(A), (C) and (D) only |
The correct answer is Option (2) → (A), (C) and (D) only Core Concept Fehling’s solution gives a positive test with aliphatic aldehydes but not with aromatic aldehydes. Explanation Option A: CH₃CHO (Acetaldehyde) This is an aliphatic aldehyde. It reduces Fehling’s solution to form red precipitate of Cu₂O. Option B: C₆H₅CHO (Benzaldehyde) This is an aromatic aldehyde. Due to resonance stabilization of –CHO group with benzene ring, it does not reduce Fehling’s solution. Option C: CH₃CH₂CHO (Propanal) This is also an aliphatic aldehyde. Hence, it gives positive Fehling’s test. Option D: HCHO (Formaldehyde) Formaldehyde is the simplest aliphatic aldehyde. It readily reduces Fehling’s solution. |