Identify the interrmediate (Y) in the following reaction for the commercial method of manufacturing of benzaldehyde? |
The correct answer is Option (2) → The intermediate $Y$ is benzal chloride ($C_6H_5-CHCl_2$). Complete statement: In the commercial manufacture of benzaldehyde from toluene, the intermediate formed is benzal chloride ($C_6H_5-CHCl_2$). Reasoning: 1. The starting compound is toluene ($C_6H_5-CH_3$). 2. Treatment with $Cl_2 / hv$ (sunlight) causes free-radical side-chain chlorination, not ring chlorination. 3. The methyl group is successively chlorinated: $C_6H_5-CH_3 → C_6H_5-CH_2Cl → C_6H_5-CHCl_2$ (benzal chloride) 4. On hydrolysis with hot water at 373 K, benzal chloride is converted into benzaldehyde ($C_6H_5-CHO$). Therefore, the correct intermediate Y is: $C_6H_5-CHCl_2$ (benzal chloride) |