The unit of rate constant for -2.5 order reaction is: |
$ (\text{mol}\ \text{L}^{-1})^{-3/2}\ \text{s}^{-1} $ $ (\text{mol}\ \text{L}^{-1})^{7/2}\ \text{s}^{-1} $ $ (\text{mol}\ \text{L}^{-1})^{-7/2}\ \text{s}^{-1} $ $ (\text{mol}\ \text{L}^{-1})^{3/2}\ \text{s}^{-1} $ |
$ (\text{mol}\ \text{L}^{-1})^{7/2}\ \text{s}^{-1} $ |
The correct answer is Option (2) → $ (\text{mol}\ \text{L}^{-1})^{7/2}\ \text{s}^{-1} $ For an $n$-th order reaction, the unit of the rate constant $k$ is given by: $\text{Unit of } k = (\text{concentration})^{1-n} \cdot (\text{time})^{-1}$ Since concentration is expressed in $\text{mol}\ \text{L}^{-1}$ and time in seconds ($\text{s}$): $\text{Unit of } k = (\text{mol}\ \text{L}^{-1})^{1-n}\ \text{s}^{-1}$ Given $n = -2.5$: $1 - n = 1 - (-2.5) = 1 + 2.5 = 3.5 = \frac{7}{2}$ $\text{Unit of } k = (\text{mol}\ \text{L}^{-1})^{7/2}\ \text{s}^{-1}$ |