Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Aldehydes, Ketones and Carboxylic Acids

Question:

Arrange the following compounds in increasing order of their acidity.

(A) Phenol
(B) Ethanol
(C) Benzoic acid
(D) p-Nitrobenzoic acid

Choose the correct answer from the options given below:

Options:

(A), (B), (C), (D)

(A), (B), (D), (C)

(B), (A), (C), (D)

(C), (B), (D), (A)

Correct Answer:

(B), (A), (C), (D)

Explanation:

The correct answer is Option (3) → (B), (A), (C), (D)

Acidity depends on the stability of the conjugate base.

  1. Ethanol (B) – aliphatic alcohol, conjugate base (ethoxide) not stabilized → least acidic
  2. Phenol (A) – conjugate base (phenoxide) stabilized by resonance → more acidic than ethanol
  3. Benzoic acid (C) – carboxylate ion stabilized by resonance → more acidic than phenol
  4. p-Nitrobenzoic acid (D) – carboxylate stabilized by electron-withdrawing NO₂ groupmost acidic

Increasing order of acidity: $\text{B < A < C < D}$

Ethanol < Phenol < Benzoic acid < p-Nitrobenzoic acid