Which of the following compounds can be prepared by Sandmeyer's reaction? (A) Chlorobenzene Choose the correct answer from the options given below: |
(A), (B) and (C) only (A), (B) and (D) only (A), (B), (C) and (D) (B), (C) and (D) only |
(A), (B) and (C) only |
The correct answer is Option (1) → (A), (B) and (C) only Sandmeyer reaction converts aryl diazonium salts into aryl halides or nitriles using cuprous salts: Fluorobenzene is not formed by Sandmeyer; it is obtained via Balz-Schiemann reaction. Option-wise Explanation (A) Chlorobenzene Prepared by treating benzene diazonium chloride with $Cu_2Cl_2$. Classic Sandmeyer transformation. (B) Bromobenzene Obtained using $Cu_2Br_2$ with diazonium salt. Also a Sandmeyer reaction. (C) Cyanobenzene Formed with $Cu_2CN_2$. This is another Sandmeyer variant. (D) Fluorobenzene – No. Fluorobenzene is prepared by the Balz–Schiemann reaction, not Sandmeyer reaction. |