Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Alcohols, Phenols and Ethers

Question:

Arrange the following compounds in increasing order of their acidity:

(A) Phenol
(B) 4-methylphenol
(C) 3-nitrophenol
(D) 4-nitrophenol

Choose the correct answer from the options given below:

Options:

(B), (A), (C), (D)

(A), (C), (B), (D)

(B), (D). (A), (C)

(C), (B), (D), (A)

Correct Answer:

(B), (A), (C), (D)

Explanation:

The correct answer is Option (1) → (B), (A), (C), (D)

To arrange them in increasing acidity, consider the effects:

  • NO₂ (nitro group) = strong electron-withdrawingincreases acidity
    Para-nitro > meta-nitro
  • CH₃ (methyl group) = electron-donatingdecreases acidity
  • Phenol is in between.

Order of acidity (least → most):

4-methylphenol (B) < Phenol (A) < 3-nitrophenol (C) < 4-nitrophenol (D)