Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: Coordination Compounds

Question:

What is the EAN of cobalt in the complex [Co(NH3)6]Cl3?

Options:

35

34

36

66

Correct Answer:

36

Explanation:

EAN is effective atomic number and it is represented as:

EAN = Z - (O.N) + 2(C.N) or number of lone pairs donated to central atom

where Z = atomic number

O.N. = oxidation number

C.N. = coordination number

[Co(NH3)6]Cl→ [Co(NH3)6]3+ + 3Cl

In [Co(NH3)6]3+ 

x + 6(0) = +3

x = 3

Co3+ (Z = 27) 

EAN = 27 - 3 + 2(6) = 24 + 12 = 36