Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Chemical Kinetics

Question:

Match the statement given in List-I with statements given in List-II

List-I

List-II

(A) Catalysts alter the rate of reaction

(I) cannot be fraction or zero

(B) Molecularity

(II) by lowering the activation energy

(C) Second half life of a first order reaction

(III) is the same as the first

(D) e-Ea/RT

(IV) refers to the fraction of molecules with energy equal to or greater than activation energy

Choose the correct answer from the options given below:

Options:

(A)-(II), (B)-(I), (C)-(III), (D)-(IV)

(A)-(I), (B)-(II), (C)-(III), (D)-(IV)

(A)-(I), (B)-(II), (C)-(IV), (D)-(III)

(A)-(II), (B)-(I), (C)-(IV), (D)-(III)

Correct Answer:

(A)-(II), (B)-(I), (C)-(III), (D)-(IV)

Explanation:

The correct answer is Option (1) → (A)-(II), (B)-(I), (C)-(III), (D)-(IV)

(A) Catalysts alter the rate of reaction

  • Catalysts work by lowering the activation energy of the reaction.
    ✅ Match: (II)

(B) Molecularity

  • Molecularity is the number of reactant molecules taking part in a single step of a reaction.

  • It is always a whole number, never zero or fractional.
    ✅ Match: (I)

(C) Second half-life of a first order reaction

  • For a first-order reaction, the half-life does not depend on concentration, so the second half-life is same as the first.
    ✅ Match: (III)

(D) e⁻ᴱᵃ/ᴿᵀ

  • This is the Arrhenius factor, representing the fraction of molecules having energy equal to or greater than activation energy.
    ✅ Match: (IV)