Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Chemical Kinetics

Question:

Match the entries of column I with appropriate entries of column II and choose the correct option out of the four options given.

Column I Column II
(a) Collision frequency (i) R = PZe-Ea/RT
(b) Fraction of molecules with energy ≥ Ea (ii) P
(c) Probability of steric factor (iii) e-Ea/RT
(d) Rate of reaction (iv) Z
Options:

(a)-(i), (b)-(iii), (c)-(ii), (d)-(iv)

(a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)

(a)-(iii), (b)-(iv), (c)-(ii), (d)-(i)

(a)-(iv), (b)-(ii), (c)-(i), (d)-(iii)

Correct Answer:

(a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)

Explanation:

The number of collisions per second per unit volume of the reaction mixture is called collision frequency (Z)

For a bimolecular reaction, A + B → products

Rate = PZABe-Ea/RT

where P = Probability of steric factor

ZAB = collision frequency of reactants A and B

e-Ea/RT = fraction of molecules with energy ≥ Ea